Evaluation of retention time for temperature-programmed gas chromatography by use of a closed-form integral.

نویسندگان

  • Tsuyoshi Kaneko
  • Iwao Amasaki
  • Masahiro Nakada
  • Zhiming Gao
چکیده

A closed-form integral for the Arrhenius exponential was obtained by using an approximate relation instead of the usual one in a linear temperature program. The closed-form integral can be applied to predict the retention time very well both for a packed column and for a capillary column, in constant the velocity mode.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Rapid temperature-programmed separation and retention prediction on a novel packed-capillary column in gas chromatography.

Novel packed-capillary columns for gas chromatography were developed with a thin-wall stainless-steel capillary of 1.0 mm i.d.; and rapid temperature-programmed separations have been carried out after a basic evaluation concerning the compatibility of these columns to the temperature program. With a numerical integration method, the retention of several test analytes during temperature-programm...

متن کامل

Predicting the Hydrate Formation Temperature by a New Correlation and Neural Network

Gas hydrates are a costly problem when they plug oil and gas pipelines. The best way to determine the HFT and pressure is to measure these conditions experimentally for every gas system. Since this is not practical in terms of time and money, correlations are the other alternative tools. There are a small number of correlations for specific gravity method to predict the hydrate formation. As th...

متن کامل

Solvability of infinite system of nonlinear singular integral equations in the C(Itimes‎ I‎, ‎c) space and modified semi-analytic method to find a closed-form of solution

‎In this article‎, ‎we discuss about solvability of infinite systems of singular integral equations with two variables in the Banach sequence space $C(I times I‎, ‎c)$ by applying measure of noncompactness‎ and Meir-Keeler condensing operators‎. By presenting an example, we have illustrated our results‎. ‎For validity of the results we introduce a modified semi-analytic method in the case of tw...

متن کامل

A method of calculating the second dimension retention index in comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry.

A method was developed to calculate the second dimension retention index of comprehensive two-dimensional gas chromatography time-of-flight mass spectrometry (GC×GC/TOF-MS) data using n-alkanes as reference compounds. The retention times of the C(7)-C(31) alkanes acquired during 24 isothermal experiments cover the 0-6s retention time area in the second dimension retention time space, which make...

متن کامل

Separation of triglycerides by gas-liquid chromatography.

The parameters affecting the separation and quantification of triglycerides by gas-liquid chromatography have been investigated with the use of QF-1 and SE-30 as stationary phases and a flame ionization detector. The isothermal characteristics of a wide variety of triglycerides (carbon number 6 to 60) on both columns show that long retention volume is directly proportional to carbon number and ...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Analytical sciences : the international journal of the Japan Society for Analytical Chemistry

دوره 24 3  شماره 

صفحات  -

تاریخ انتشار 2008